| 白茹,刘鹏程,刘婧靖,王晓娟,谢宇蓉,谭春红.链状银硫簇合物的合成和晶体结构[J].南华大学学报(自然科学版),2019,33(2):85~89.[BAI Ru,LIU Pengcheng,LIU Jingjing,WANG Xiaojuan,XIE Yurong,TAN Chunhong.Synthesis and Crystal Structure of a Silver Sulfur Cluster Coordination Compound[J].Journal of University of South China(Science and Technology),2019,33(2):85~89.] |
| 链状银硫簇合物的合成和晶体结构 |
| Synthesis and Crystal Structure of a Silver Sulfur Cluster Coordination Compound |
| 投稿时间：2018-09-04 |
| DOI： |
| 中文关键词: 银 有机硫醇 一维链状簇合物 晶体结构 |
| 英文关键词:silver organic thiol one-dimensional chain with Ag6-S6 cluster crystal structure |
| 基金项目:湖南省教育厅一般项目(17C1358);南华大学博士科研启动基金项目(2015XQD11;2010XQD13) |
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| 中文摘要: |
| 选用叔丁硫醇和硝酸银在碱性条件下通过溶剂热反应制得一例新的银-硫配合物晶体[Ag6(μ-StBu)6]n (1),对其进行X-射线单晶衍射、元素分析表征。结构分析表明1是以6核银Ag6(μ-StBu)6为簇基结构基元的一维链状簇合物。 |
| 英文摘要: |
| Reaction of tert-butyl mercaptan and silver nitrate under alkaline condition has obtained the crystal [Ag6(μ-StBu)6]n (1).It was characterized by X-ray single crystal diffraction and elemental analysis.The structural analysis showed that 1 was one-dimensional chain based on the hexa-nuclear silver Ag6(μ-StBu)6 cluster. |
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