| 孙允凯,王梦蝶,王小峰.单手性螺旋聚醚的合成与应用研究进展[J].南华大学学报(自然科学版),2018,32(6):52~59.[SUN Yunkai,WANG Mengdie,WANG Xiaofeng.The Process of Synthesis and Application of Single-handed Helical Polyethers[J].Journal of University of South China(Science and Technology),2018,32(6):52~59.] |
| 单手性螺旋聚醚的合成与应用研究进展 |
| The Process of Synthesis and Application of Single-handed Helical Polyethers |
| 投稿时间：2018-06-03 |
| DOI： |
| 中文关键词: 螺旋聚醚 环氧化合物 阴离子聚合 不对称催化 |
| 英文关键词:helical polyether epoxide anionic polymerization asymmetric catalysis |
| 基金项目:国家自然科学基金项目(11305086);湖南省自然科学基金项目(14JJ6021);大学生研究性学习和创新性实验计划资助项目(316) |
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| 中文摘要: |
| 螺旋聚合物是化学家研究的热点之一.单手性螺旋聚醚作为螺旋聚合物中的一大类,近十余年来引起人们的广泛关注.介绍在手性环氧丙烷3号位碳上引进大位阻基团,通过阴离子聚合合成单手性螺旋聚醚,并介绍其在手性识别、不对称催化等方面的应用研究. |
| 英文摘要: |
| The helical-polymers is one of the hot research topics to the chemists.Single-handed helical polyether is a kind of spiral polymers,which has attracted much attention in past decade.In this review,the single-handed helical polyether with a bulky group at the 3-position carbon of chiral epoxide derivatives synthesized by anionic polymerization,was introduced.On the other hand,its potential application,such as chiral recognition,asymmetric catalysis,was presented. |
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