| 许丽,王娇,蒋敏,彭鹏程,肖锡林.新型2,5-二取代-1,3,4-噻二唑类化合物的合成及性能研究[J].南华大学学报(自然科学版),2017,31(1):101~106, 112.[XU Li,WANG Jiao,JANG Min,PENG Peng-cheng,XIAO Xi-lin.Synthesis and Properties of Novel 2,5-Disubstituted1,3,4-Thiadiazole Compounds[J].Journal of University of South China(Science and Technology),2017,31(1):101~106, 112.] |
| 新型2,5-二取代-1,3,4-噻二唑类化合物的合成及性能研究 |
| Synthesis and Properties of Novel 2,5-Disubstituted1,3,4-Thiadiazole Compounds |
| 投稿时间：2016-06-30 |
| DOI： |
| 中文关键词: 噻二唑 重氮化 合成 配位 |
| 英文关键词:thiadiazole diazotization synthesis coordination |
| 基金项目:国家自然科学基金项目(31200140) |
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| 中文摘要: |
| 1,3,4-噻二唑类杂环化合物不仅具有优良的杀虫,除草,抗植物病毒,杀菌、抗菌等生物活性,而且具有选择性好,活性高,毒性低,环境相容性好等优点,在医药和农药的研究和开发中发挥着重要作用.本文通过噻二唑重氮化后经过偶合反应合成了系列新型化合物,并用1HNMR、IR和元素分析对目标化合物进行了结构表征,研究了它们与过渡金属离子的显色配位反应,为其在医药方面的应用提供实验基础. |
| 英文摘要: |
| 1,3,4-thiadiazole oxadiazole heterocyclic compounds play an important role in the research and development of medicines and pesticides because of their excellent insecticidal,weeding,anti plant virus,sterilization,antibacterial biological activities and the advantages of high selectivity,high biological activity,low toxicity,and good environmental compatibility.In this paper,through thiadiazole diazotization by coupling reaction,three new series of compounds were synthesized and identified by means of 1HNMR,IR and elementary analysis.A preliminary study of their coordination reaction with the transition metal ions was carried out,to provide the experimental basis for their application in medicine. |
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