张剑,王梦蝶,王小峰,谭春红.两个镉配位聚合物的合成和晶体结构[J].南华大学学报(自然科学版),2020,34(4):80~84.[ZHANG Jian,WANG mengdie,WANG Xiaofeng,TANG Chunhong.The Synthesis and Crystal Structure of Two Cadmium Coordination Polymers[J].Journal of University of South China(Science and Technology),2020,34(4):80~84.] |
两个镉配位聚合物的合成和晶体结构 |
The Synthesis and Crystal Structure of Two Cadmium Coordination Polymers |
投稿时间:2020-02-04 |
DOI: |
中文关键词: 镉 配合物 合成 晶体结构 |
英文关键词:cadmium coordination polymer synthesis crystal structure |
基金项目:湖南省教育厅一般项目(2017SJY27);南华大学博士科研启动基金项目(2015XQD11;2010XQD13) |
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中文摘要: |
选用2,2-联吡啶和二羧酸配体,在溶剂热条件下与硝酸镉反应,制得配位聚合物n(1)和n(2)。对这两个配位聚合物进行X-射线单晶衍射、元素分析表征,结构分析表明配位聚合物1和2都是一维链状结构。 |
英文摘要: |
Two new cadmium coordination polymers n(1),n(2)were successfully prepared under solvothermal reaction of fumaric acid( or terephthalic acid),2,2-bipyridine and cadmium nitrate in N,N′-dimethylformamide.The two coordination polymers 1 and 2 were characterized by X-ray single crystal diffraction and elemental analysis.The structural analysis showed that 1 and 2 were both one-dimensional chain structures. |
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