| 肖锡林,张迪,王志梅,郦志阳,苏昌霖,彭鹏程.四齿席夫碱类光学探针用于检测铀和含磷酸基团生物分子的研究进展[J].南华大学学报(自然科学版),2019,33(5):1~12, 18.[XIAO Xilin,ZHANG Di,WANG Zhimei,LI Zhiyang,SU Changlin,PENG Pengcheng.Research Progress of Tetradentate Schiff Base Optical Probes for Detecting Uranium and Biomolecules Containing Phosphate Groups[J].Journal of University of South China(Science and Technology),2019,33(5):1~12, 18.] |
| 四齿席夫碱类光学探针用于检测铀和含磷酸基团生物分子的研究进展 |
| Research Progress of Tetradentate Schiff Base Optical Probes for Detecting Uranium and Biomolecules Containing Phosphate Groups |
| 投稿时间：2019-05-27 |
| DOI： |
| 中文关键词: 四齿席夫碱 铀酰 磷酸基团 光学探针 配位化学 |
| 英文关键词:tetradentate Schiff base uranyl phosphate group optical probe coordination chemistry |
| 基金项目:国家自然科学基金项目(11475079) |
|
| 摘要点击次数: 1159 |
| 全文下载次数: 924 |
| 中文摘要: |
| 席夫碱具有易制备、检测金属离子灵敏度高和选择性好等特点,长期以来受到人们的广泛关注。近年来四齿席夫碱类光学探针在医学、催化、分析化学、超分子化学、功能材料及配位化学等领域得到广泛应用。本文结合实时热点,阐述了四齿席夫碱类光学探针利用其特有的NN或NO型空腔与铀酰离子配位,实现对实际样品中铀酰离子的定性分析和定量检测,并成功应用于含磷酸基团生物分子的识别与检测。最后展望并探讨了四齿席夫碱类光学探针的研究发展方向。 |
| 英文摘要: |
| Schiff base has the characteristics of easy preparation,high sensitivity and high selectivity,and has been widely concerned by people for a long time.In recent years,tetradentate Schiff base optical probes have been widely used in the fields of medicine,catalysis,analytical chemistry,supramolecular chemistry,functional materials and coordination chemistry.In this paper,combined with real-time hotspots,the tetradentate Schiff base optical probes are characterized by their unique NN or NO-type cavities and uranyl ion coordination to achieve qualitative analysis and quantitative detection of uranyl ions in actual samples and applied to the identification and detection of biomolecules containing phosphate groups.Finally,the research and development direction of the tetradentate Schiff base optical probe is prospected and discussed. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| 关闭 |
|
|
|