廖云,邓昌爱,谭倪,杜可杰.热塑性聚氨酯/凹凸棒土纳米复合材料力学行为研究[J].南华大学学报(自然科学版),2013,27(3):82~85.[LIAO Yun,DENG Chang-ai,TAN Ni,DU Ke-jie.Study on the Mechanical Behavior of TPU/AT Nanocomposite[J].Journal of University of South China(Science and Technology),2013,27(3):82~85.]
热塑性聚氨酯/凹凸棒土纳米复合材料力学行为研究
Study on the Mechanical Behavior of TPU/AT Nanocomposite
  
DOI:
中文关键词:  热塑性聚氨酯  凹凸棒土  力学行为
英文关键词:thermoplastic polyurethane  attapulgite  mechanical behavior
基金项目:
作者单位
廖云,邓昌爱,谭倪,杜可杰 南华大学 化学化工学院,湖南 衡阳 421001 
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中文摘要:
      通过溶液共混法制备了热塑性聚氨酯(TPU) /凹凸棒土(AT)纳米复合材料,研究AT的加入对TPU基体滞后、拉伸应力软化行为和松弛效应的影响.研究结果显示:随着AT的加入,纳米复合材料的滞后圈增大,拉伸应力软化效应增强,应力松弛速率和程度降低.TPU/AT体系分子链运动模型表明纳米复合材料力学行为的改变,可能是因为AT和TPU基体间形成了氢键,阻碍了分子链的运动。
英文摘要:
      Thermoplastic polyurethane/attapulgite (TPU/AT) nanocomposites were prepared via solution blending process.The influence of hysteresis,stress softening behavior and stress relaxation effect of the AT on TPU matrix were investigated.The results demonstrated that with the addition of AT,the hysteresis loops were bigger,the stress softening effects were more obvious and the rate and degree of stress relaxation were reduced than those of pure TPU.The molecular motion model of TPU/AT system indicated that the influence of mechanical behavior of AT on TPU matrix was possibly related with density of the hydrogen bond between AT-TPU,which may block the movement of chains.
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