王延飞,阳鹏飞,陈仲清,刘慧君,沈本贤.DMTDA在聚氨酯弹性体中的扩链性能研究[J].南华大学学报(自然科学版),2010,24(2):99~102.[WANG Yan-fei1,2,YAN Peng-fei1,CHEN Zhong-qing1,LIU Hui-jun1,SHEN Ben-xian2.Research of Property of DMTDA as Chain Extender and Curing Agent of Polyurethane Elastomers[J].Journal of University of South China(Science and Technology),2010,24(2):99~102.]
DMTDA在聚氨酯弹性体中的扩链性能研究
Research of Property of DMTDA as Chain Extender and Curing Agent of Polyurethane Elastomers
投稿时间:2010-01-07  
DOI:
中文关键词:  聚氨酯  扩链剂  固化剂
英文关键词:polyurethane  chain extender  curing agent
基金项目:中国石油化工集团公司基金项目(203072)
作者单位
王延飞1,2,阳鹏飞1,陈仲清1,刘慧君1,沈本贤2 1.南华大学 化学化工学院,湖南 衡阳 421001
2.华东理工大学 化工学院,上海 200237 
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中文摘要:
      在聚氨酯弹性体加工成型中必须加入一种兼起扩链和交联作用的固化剂,一般使用的扩链剂是3,3’-二氯-4,4’-二氨基-二苯基甲烷 (英文缩写为MOCA),在本文的研究中,以自制的二甲硫基甲苯二氨 (英文缩写为DMTDA)作为扩链固化剂,并考察了它的扩链性能,研究发现:对聚酯型聚氨酯弹性体而言,制备的DMTDA的扩链效果与国外同类产品ETHACURE300的扩链效果相当;而且在邵氏硬度方面,自制的DMTDA要优于ETHACURE300.结果表明:自制的DMTDA可以替代国外同类产品ETHACURE300在聚酯型聚氨酯弹性体中使用.
英文摘要:
      4,4,-methylene-bis(2-chloroaniline) (MOCA) is often used as chain extender and curing agent in the processing of polyurethane elastomers.The mechanical properties of polyurethane elastomers cured by 3,5-dimetylthio-2,4-diaminotolune(DMTDA)and ETHACURE300 is researched in this work.It is found that the properties of polyurethane elastomers extended and cured by DMTDA is similar to ETHACURE300,and DMTDA from laboratory will take place of ETHACURE300 in the processing of polyurethane elastomers as chain extender and curing agent.
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