| 袁金涛,廖力夫,刘传湘,杨静,何博.pH渐变光谱秩消失因子分析法测定混合物中的2,4-二硝基苯酚[J].南华大学学报(自然科学版),2007,21(3):93~96.[.Determination of 2,4 -Dinitrophenol in Mixtures by pH Changed Gradually Spectral Rank Annihilation Factor Analysis[J].Journal of University of South China(Science and Technology),2007,21(3):93~96.] |
| pH渐变光谱秩消失因子分析法测定混合物中的2,4-二硝基苯酚 |
| Determination of 2,4 -Dinitrophenol in Mixtures by pH Changed Gradually Spectral Rank Annihilation Factor Analysis |
| 修订日期：2007-03-14 |
| DOI： |
| 中文关键词: 2 4-二硝基苯酚 pH渐变光谱 秩消失因子分析法 混合物 |
| 英文关键词:2,4-dinitrophenol,pH Changed gradually Spectral,rank annihilation factor analysis,mixture |
| 基金项目: |
| 袁金涛 廖力夫 刘传湘 杨静 何博 |
| [1]南华大学公共卫生学院 [2]南华大学化学化工学院 [3]湖南衡阳 |
| 摘要点击次数: 887 |
| 全文下载次数: 1 |
| 中文摘要: |
| 建立了pH渐变光谱秩消失因子分析法测定混合物中2,4-二硝基苯酚的新方法.在本方法中,以向Britton-Robinson缓冲溶液中滴加氢氧化钠溶液的方式使溶液pH不断变化,通过记录多个pH点溶液的吸收光谱获得酸度-光谱双线性数据矩阵,再应用秩消失因子分析法计算混合物中2,4-二硝基苯酚的浓度.应用本方法对混合物样品中2,4-二硝基苯酚的进行了测定,结果满意. |
| 英文摘要: |
| A new method for the determination of 2,4-dinitrophenol in mixtures by pH changed gradually spectral rank annihilation factor analysis has been developed.In the method described here,the pH of the Britton-Robinson buffer solution containing 2,4-dinitrophenol was changed gradually by adding sodium hydroxide solution into the solution.In this process,the spectrum of the solutin at different pH has been recorded and then the acidity-absorbance spectra matrix was obtained.Thus the concentration of 2,4-dinitrophenol in the mixtures can be obtained by rank annihilation factor analysis.The method is free to separate 2,4-dinitrophenol from mixtures,so the method is simple and convenient.The method has been used to the determination of 2,4-dinitrophenol in environmental mixture samples,with satisfactory results. |
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