| 贾晓辉,薛永强.高效液相催化氧化菲制取菲醌[J].南华大学学报(自然科学版),2004,(2):20~24.[.Catalytic Oxidation of Crude Phenanthrene to Phenanthrenequinone in Liquid Phase[J].Journal of University of South China(Science and Technology),2004,(2):20~24.] |
| 高效液相催化氧化菲制取菲醌 |
| Catalytic Oxidation of Crude Phenanthrene to Phenanthrenequinone in Liquid Phase |
| 修订日期：2004-03-05 |
| DOI： |
| 中文关键词: 菲,合成,菲醌,卤素化合物 |
| 英文关键词:phenanthrene,synthesis,phenanthrenequinone,halogen compound |
| 基金项目:山西省教育厅科技开发项目(99011)，山西省自然科学基金资助项目(20021016). |
| 贾晓辉 薛永强 |
南华大学化学化工学院 湖南衡阳421001
(贾晓辉)
，太原理工大学化学系 山西太原030024(薛永强)
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| 中文摘要: |
| 以纯度为84.21%的工业菲为原料,冰醋酸作溶剂,卤素化合物作为氧化剂氧化菲合成菲醌的氧化体系,菲醌最高收率可达63.23%,并确定了影响此反应的主要因素和最佳反应条件.该工艺反应条件温和,操作简单,无"三废"污染问题,溶剂可循环利用. |
| 英文摘要: |
| In the paper,phenanthrenequinone was prepared by oxidation of phenanthrene((84.21%)) with halogen compound in the presence of glacial acetic acid.The yield of phenanthrenequinone can reach 63.23%.Chief influential factors and optimum processing condition of this reaction were discussed.The reaction condition is moderate;the technological process is comparatively simple;the environment is not polluted,and the solvent can be recycled. |
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